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Full Description
This book provides an effective review and critical analysis of the recently demonstrated room-temperature sodium-sulfur batteries. Divided into three sections, it highlights the status of the technologies and strategies developed for the sodium metal anode, insight into the development of sulfur cathode, and electrolyte engineering. It reviews past, present, and future perspectives for each cell component including characterization tools unveiling the fundamental understanding of the room-temperature sodium-sulfur batteries.
FEATURES:
Highlights scientific challenges in developing room-temperature sodium-sulfur batteries
Covers pertinent anode, cathode, and electrolyte engineering
Provides scientific and technical interpretation for each of the cell components
Discusses how Na-S batteries relate to the more extensively researched Li-S batteries
Explores importance of the SEI and CEI in developing stable sodium-sulfur batteries
This book is aimed at graduate students and researchers in energy science, materials science, and electrochemistry.
Contents
Chapter 1. Introduction: Sodium Sulfur battery technology. 1.1 Introduction: Sodium Sulfur battery technology. 1.2 Brief history of Sodium Sulfur battery. 1.3 Sodium-metal batteries and the operation of high-temperature Sodium-Sulfur Batteries. 1.4 The transition from high-temperature to room-temperature sodium-sulfur Batteries. 1.5 Development of the RT Na-S batteries. 1.6 Conclusion and Prospects. References. Chapter 2. Sodium metal anode: Past, Present, and Future of sodium metal anode. 2.1 Introduction to the sodium metal anode. 2.2 Challenges in developing a stable sodium metal anode. 2.3 Strategies to overcome the challenges. 2.4 Future prospects. References. Chapter 3. Sulfur Cathode: Progress in the development of sulfur cathode. 3.1 Introduction to Sulfur Cathode. 3.2 Challenges in developing the stable sulfur cathodes. 3.3 Progress in developing sulfur cathodes. 3.4 Importance of electrolyte/sulfur (E/S) ratio in developing a stable sulfur cathode. 3.5 Strategies to develop high-loading sulfur cathodes. 3.6 Future prospects. References. Chapter 4. Electrolytes for room-temperature sodium-sulfur batteries: A holistic approach to understand solvation. 4.1 Basic properties of the electrolytes for alkali metal batteries. 4.2 The Solid-electrolyte interphase (SEI) and the Importance of sodium-ion solvation. 4.3 Liquid electrolyte to quasi-solid-state electrolyte to solid electrolyte for sodium-sulfur batteries. 4.4 Nature of electrolyte and its role in developing a stable SEI and CEI. 4.5 Future prospects. References. Chapter 5. Analytical Techniques to Probe Room-Temperature Sodium-Sulfur Batteries. 5.1 Introduction. 5.2 Overview of the routine techniques to probe sodium metal anode. 5.3 Overview of the routine techniques to probe sulfur cathode. 5.4 In-situ/Operando techniques for sodium-sulfur batteries. 5.5 Future prospects. References. Chapter 6. Sodium sulfur batteries: similarities and differences with Lithium-sulfur battery. 6.1. Na-S and Li-S chemistries are fundamentally different- a mechanistic overview. 6.2 Polysulfide Species Dissolution. 6.3 Electrolyte for Li-S and RT Na-S batteries. 6.4 Future Prospect. References. Chapter 7. Other Sodium Metal Based Rechargeable Battery Technologies: A Brief Introduction to Sodium Dual Ion Batteries. 7.1 Bird-eye view of the sodium metal-based batteries. 7.2 Overview of sodium air battery. 7.3 Overview of sodium dual-ion batteries. 7.4 Future Prospects. References. Chapter 8. Conclusion and Prospects.