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基本説明
Presents a comprehensive list of cumulene systems and their reactions, with chapters are structured according to the number of carbon atoms in the system.
Full Description
Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of "click reactions". Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature. The chapters are structured according to the number of carbon atoms in the system, including coverage of:
introduction to the chemistry of cumulenes
one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts
two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes
1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes
1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides
1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes
noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation
Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry.
Contents
Preface Acknowledgements
1 General Introduction
References
2 1-Carbon Cumulenes
2.1 Sulfines, R2C SO
2.2 Sulfenes, R2C S(O)O
2.3 Other 1-Carbon Cumulenes
3 2-Carbon Cumulenes
3.1 Carbon Oxides, O C O, :CO
3.2 Carbon Sulfides, S C S, S CO
3.3 Carbon Nitrides
3.4 Center Carbon Phosphorallenes, P C P
4 1,2-Dicarbon Cumulenes
4.1 Ketenes, R2C C O
4.2 Thioketenes, R2C C S
4.3 Ketenimines, R2C C NR
4.4 1-Silaallenes, R2C C Si
4.5 1-Phosphaallenes, R2C C P
4.6 Other Metal Allenes
5 1,3-Dicarbon Cumulenes
5.1 Thiocarbonyl S-ylides, R2C S CH2
5.2 2-Azaallenium Salts, R(Ce)C N+ C(Ce)R
5.3 1-Oxa-3-azoniabutatriene Salts, R2C N+ C O
5.4 1-Thia-3-azabutatriene Salts, R2C N+ C S
5.5 Phosphorus Ylides
6 1,2,3-Tricarbon Cumulenes
6.1 Allenes, R2C CR2
6.2 [3] Cumulenes, R2C C C CR2
6.3 [4] Cumulenes, R2C C C C CR2
6.4 [5] Cumulenes, R2C C C C C CR2
7 Noncarbon Cumulenes
7.1 Azides, RN N N
7.2 Triazaallenium Salts, RN N+ NR
7.3 Sulfur Oxides
7.4 Sulfur Nitrides
7.5 Cationic Boron Cumulenes, R2N B NR
Index
