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基本説明
日本化学会第89春季年会(2009)好評書。
Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power’s 1980 book “Metal and Metalloid Amides.”
An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals; alkaline earth metals; zinc, cadmium and mercury
the transition metals; group 3 and lanthanide metals; group 13 metals; and more.
Full Description
Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power's 1980 book "Metal and Metalloid Amides." An introduction to the topic is followed by in-depth discussions of the amide compounds of:
alkali metals
alkaline earth metals
zinc, cadmium and mercury
the transition metals
group 3 and lanthanide metals
group 13 metals
silicon and the group 14 metals
group 15 metals
the actinide metals
Accompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.
Contents
Biographies. Preface.
1. Introduction.
1.1. Scope and Organisation of Subject Matter.
1.2. Developments and Perspectives.
2. Alkali Metal Amides.
2.1. Introduction.
2.2. Lithium Amides.
2.3. Sodium Amides.
2.4. Potassium Amides.
2.5. Rubidium Amides.
2.6. Caesium Amides.
3. Beryllium and the Alkaline Earth Metal Amides.
3.1. Introduction.
3.2. Beryllium Amides.
3.3. Magnesium Amides.
3.4. Calcium Amides.
3.5. Strontium Amides.
3.6. Barium Amides.
4. Amides of the Group 3 Lanthanide Metals.
4.1. Introduction.
4.2. The Pre-1996 Literature: Anwander's Review.
4.3. The Recent (Post-1995) Literature.
5. Amides of the Actinide Metals.
5.1. Introduction
5.2.Neutral Amidouranium (IV) and Thorium (IV) Complexes.
5.3. Neutral UIII Amides.
5.4. Neutral Mixed Valence (UIII/UIV), UII UV and UVI Amides.
5.5. Amidouranates.
5.6. Amidouranium Tetraphenylborates.
6. Amides of the Transition Metals.
6.1. Introduction.
6.2. Transition Metal Derivatives of Monodentate Amides.
6.3. Transition Metal Complexes of Polydentate Amido Ligands.
6.4. Other Chelating Amido Ligands.
7. Amides of Zinc, Cadmium and Mercury.
7.1. Introduction.
7.2. Neutral Homoleptic Zinc, Cadmium and Mercury Amides.
7.3. Ionic Metal Amides.
7.4. Lewis Base Complexes, Chelated Metal Amides and Heteroleptic Amido Complexes.
8. Amides of the Group 13 Metals.
8.1. Introduction.
8.2. Aluminum Amides.
8.3. Gallium Amides.
8.4. Indium Amides.
8.5. Thallium Amides.
9. Subvalent Amides of Silicon and the Group 14 Metals.
9.1. Introduction.
9.2. Subvalent Amidosilicon Compounds.
9.3. Amidometal(II) Chemistry [Ge(II), Sn(II), Pb(II)].
9.4. Dimeric Metal(III) Imides: Biradicaloid Compounds.
9.5. Higher-Nuclearity Group 14 Metalloid Clusters having Amido Ligands.
10. Amides of the Group 15 Metals (As, Sb, Bi).
10.1. Introduction.
10.2. Mononuclear Group 15 Metal (III) Amides.
10.3. Oligomeric Group 15 Metal Imides.
10.4. Mononuclear Group 15 Metal (V) Amides.
10.5. Group 15 Metal (III) Macrocyclic Imides.
10.6. Miscellaneous Group 15 Metal-Nitrogen Compounds.
Index.
