- ホーム
- > 洋書
- > 英文書
- > Science / Mathematics
Full Description
This guide provides a comprehensive and authoritative review of name reactions on homologation. Each section includes a description of the reaction, the historical perspective, a mechanism for the reaction, variations and improvements on the reaction, synthetic utilities of the reaction, experimental details, and current references to the primary literature. The primary topics include organometallics (palladium, organozinc, organocopper, other organometallics), carbon-chain homologation, (rearrangement, concerted rearrangement, cationic rearrangement, anionic rearrangement, other rearrangements), radical chemistry, asymmetric C-C bond formation, and other types (such as Cannizzaro disproportionation, Eschenmoser coupling, Mannich, Mitsunobu, Passerini, and Ugi).
Contents
TOC for PART 1
Foreword. Preface.
Contributing Authors.
Chapter 1: Organometallics.
Section 1.1 Palladium Chemistry.
Section 1.2 Organocopper Reagents.
Section 1.3 Other Organometallic Reagents.
Chapter 2: Carbon-Chain Homologations.
2.1 Arndt-Eistert homologation.
2.2 Morita-Baylis-Hillman reaction.
2.3 Benzoin condensation.
2.4 Corey-Fuchs reaction.
2.5 Henry reaction.
2.6 Horner-Wadsworth-Emmons reaction.
2.7 Julia-Lythgoe olefination.
2.8 Knoevenagel condensation.
2.9 Mukaiyama aldol reaction.
2.10 Peterson olefination.
2.11 Sakurai allylation reaction.
2.12 Stetter reaction.
2.13 Wittig reaction.
Chapter 3: Radical Chemistry.
3.1 Barton-McCombie deoxygenation.
3.2 Barton nitrite photolysis.
3.3 Sandmeyer reaction.
3.4 Wohl-Ziegler reaction.
Appendixes.
Appendix 1, Table of Contents for Volume 1: Name Reactions in Heterocyclic Chemistry.
Appendix 2, Table of Contents for Volume 2: Name Reactions for Functional Group Transformations.
Appendix 3, Table of Contents for Volume 4: Name Reactions for Homologations-2.
TOC for PART 2:
Foreword.
Preface.
Contributing Authors.
Chapter 1: Rearrangements.
Section 1.1 Concerted rearrangement.
Section 1.2 Cationic rearrangement.
Section 1.3 Anionic rearrangement.
Chapter 2: Asymmetric CC bond formation.
2.1 Evans aldol reaction.
2.2 Hajos-Wiechert reaction.
2.3 Keck stereoselective allylation.
2.4 Roush allylboronation.
Chapter 3: Miscellaneous homologation reactions.
3.1 Bamford-Stevens reaction.
3.2 Mannich reaction.
3.3 Mitsunobu reaction.
3.4 Parham cyclization.
3.5 Passerini reaction.
3.6 Ugi reaction.
Appendixes.
Appendix 1, Table of Contents for Volume 1: Name Reactions in Heterocyclic Chemistry.
Appendix 2, Table of Contents for Volume 2: Name Reactions for Functional Group Transformations.
Appendix 3, Table of Contents for Volume 3: Name Reactions for Homologations-I.
Appendix 4, Table of Contents for Volume 5: Name Reactions for Ring Formations.
Appendix 5, Table of Contents for Volume 6: Name Reactions in Heterocyclic Chemistry-II.
Subject index.
