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基本説明
Provides the definitive desktop reference for the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. New to this edition are 6 entirely new chapters focusing on novel approaches to catalytic asymmetric synthesis.
Full Description
Since the last edition was published seven years ago, catalytic asymmetric synthesis has become crucial to chemistry and to the preparation of pharmaceutical, fine chemical, and agricultural agents. The revised Catalytic Asymmetric Synthesis includes six new chapters on topics like non-conventional media/conditions, organocatalysis, CH activation, and much more, while the book's remaining chapters have been fully updated. A new section on carbon-carbon bond forming reactions, authored by distinguished Nobel prizewinning scientists, has been added. This revision, with a helpful appendix, is an essential reference on catalytic asymmetric synthesis for both chemists and students alike.
Contents
Preface. Preface to the Second Edition. Preface to the First Edition. Contributors. 1 Catalytic Asymmetric Synthesis in Non-ConventionalMedia/Conditions (Chikako Ogawa and Shu Kobayashi). 2 Asymmetric Organocatalysis. 2A Enantioselective Organocatalysis Involving Iminium, Enamine,SOMO and Photoredox Activation (Allan J. B. Watson and David W.C. MacMillan). 2B Asymmetric Acid-Base Bifunctional Catalysis with OrganicMolecules (Yi Wang and Li Deng). 2C Asymmetric Phase-Transfer and Ion Pair Catalysis (SeijiShirakawa and Keiji Maruoka). 3 Chiral Lewis Acids and Bronsted Acids in AsymmetricSynthesis (Hisashi Yamamoto and Cheol Hong Cheon). 4 Asymmetric Synthesis through C?H Activation (Huw M.L. Davies and Jorn Hansen). 5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions(Yoshiji Takemoto and Hideto Miyabe). 6 Enzyme-Catalyzed Asymmetric Synthesis (HaraldGroger). 7 Transition Metal-Catalyzed Homogeneous AsymmetricHydrogenation (Gao Shang, Wei Li and Xumu Zhang). 8 Asymmetric Carbon-Carbon Bond Forming Reactions. 8A Catalytic Asymmetric Conjugate Addition (Jian-Xin Ji andAlbert S. C. Chan). 8B Enantioselective Allylic Substitutions withCarbon-Nucleophiles (Gunter Helmchen,Uli Kazmaier andSebastian Forster). 8C Asymmetric Carbometallation and Carbocyclizations (IwaoOjima, Joseph J. Kaloko, Stephen J. Chaterpaul, Yu-Han Gary Tengand Chi-Feng Lin). 8D Asymmetric Ene Reactions and Cycloadditions (Koichi Mikamiand Kohsuke Aikawa). 8E Catalytic Enantioselective Olefin Metathesis Reactions(Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek and AdilR. Zhugralin). 9 Asymmetric Hydrosilation of Carbon-Carbon Double Bonds andRelated Reactions (Jin Wook Han and Tamio Hayashi). 10 Asymmetric Carbonylations (Cyril Godard, AuroraRuiz, Montserrat Dieguez, Oscar Pamies and CarmenClaver). 11 Asymmetric Oxidations and Related Reactions(Kazuhiro Matsumoto and Tsutomu Katsuki). 12 Asymmetric Amplification and Autocatalysis (KensoSoai, Tsuneomi Kawasaki, and Takanori Shibata). 13 Asymmetric Polymerization (Shingo Ito and KyokoNozaki). Index.
