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Full Description
Supercapacitors: Materials, Design, and Commercialization provides a comprehensive overview of the latest research trends and opportunities in supercapacitors, particularly in terms of novel materials and electrolytes. The book addresses the transformation in supercapacitive technology from double layer capacitance to battery-type capacitance, providing a clear understanding of the conceptual differences between various charge storage processes for supercapacitors, charge storage based on materials and electrolytes, and calculation for capacitance for these charge processes. Detailed chapters discuss recent developments in materials, such as carbons, chalcogenides, MXene and phosphorene, various polymer nanocomposites, and polyoxometalates for supercapacitors.
This is followed by in-depth coverage of electrolytes, including the evolution of electrolytes from aqueous to water-in-salt electrolytes and their role in improving the energy density of supercapacitors. The final part of the book examines the role of artificial intelligence in the design of supercapacitors, and latest developments in translating novel supercapacitor technologies from laboratory-scale research to a commercialization.
Contents
1. Introduction to supercapacitors, materials, and design
2. Nanocarbons and Electric Double Layer Capacitors (EDLC)
3. Categories of Pseudocapacitors: Intrinsic, extrinsic, and intercalation materials
4. Electrochemical characterization and calculation methods of supercapacitors
5. Transition metal oxides/sulfides electrode-based supercapacitors
6. Conducting polymers and their composites as supercapacitor electrodes
7. MOF and their derivatives for supercapacitors
8. Supercapacitors based on MXene (carbides/nitrides) and black phosphorous electrodes
9. Polyoxometalates (POMs) and redox active molecular clusters for supercapacitors
10. Conventional Supercapacitor electrolytes: Aqueous, Organic, and Ionic
11. Solid-state and gel-type supercapacitor electrolytes - polymers and cross-linkers
12. Water-in-salt electrolyte - towards high voltage aqueous supercapacitors
13. Deep eutectic solvents as green and cheap supercapacitor electrolytes
14. Device configuration: Asymmetric vs. hybrid supercapacitors
15. Machine learning and data-driven materials exploration for supercapacitors
16. Translation of supercapacitor technology from laboratory scale to commercialization
