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Full Description
Spectroscopic Techniques and Hindered Molecular Motion presents a united, theoretical approach to studying classical local thermal motion of small molecules and molecular fragments in crystals by spectroscopic techniques. Mono- and polycrystalline case studies demonstrate performance validity.
The book focuses on small molecules and molecular fragments, such as N2, HCl, CO2, CH4, H2O, NH4, BeF4, NH3, CH2, CH3, C6H6, SF6, and other symmetrical atomic formations, which exhibit local hindered motion in molecular condensed media: molecular and ionic crystals, molecular liquids, liquid crystals, polymeric solids, and biological objects. It reviews the state of studying the hindered molecular motion (HMM) phenomenon and the experimental works on the basis of the latest theoretical research.
Case Studies
Physical models of hindered molecular motion
General solution of the stochastic problem for the hindered molecular motion in crystals
Formulae of the angular autocorrelation function symmetrized on the crystallographic point symmetry groups
Formulae of the spectral line shapes concerning the dielectric, infrared, Raman, nuclear magnetic relaxation, and neutron scattering spectroscopy in the presence of the hindered molecular motion
Experimental probation of the theoretical outcomes
Proton relaxation in three-atomic molecular fragments undergoing axial symmetry hindered motion
Structural distortion in the ordered phase of crystalline ammonium chloride
Organic compounds, polymers, pharmaceutical products, and biological systems consist of the molecular fragments, which possess rotational or conformational degrees of freedom or an atomic exchange within the fragme
Contents
Fundamentals of the Theory of Hindered Molecular Motion. The General Solution of the Hindered Molecular Motion Problem. The Autocorrelation Functions Adapted to the Extended Angular Jump Model. Dielectric and Optical Spectroscopy Application. Application to the Nuclear Magnetic Resonance Spin-Lattice Relaxation. Incoherent Neutron Scattering Application.
