アライン合成化学 Comprehensive Aryne Synthetic Chemistry

Yoshida, Hiroto (EDT)

Elsevier - Health Sciences Division（2022/07発売）

• 製本 Paperback:紙装版/ペーパーバック版／ページ数 392 p.
• 言語 ENG
• 商品コード 9780323851534
• DDC分類 547.2

Full Description

Arynes have been important, well-recognized reactive intermediates in organic chemistry since the first speculation of their existence at the beginning of the 20th century. In recent years, synthetic chemistry with arynes has experienced a remarkable revival, leading to diverse new reactions that provide convenient and direct access to various aromatic compounds of high synthetic significance. Comprehensive Aryne Synthetic Chemistry summarizes the progress in the synthetic utilization of arynes for noncatalytic and transition metal-catalyzed reactions developed in the last 20 years. The book covers a broad range of topics including methods of generating arynes, regioselectivity, electrophilic couplings, pericyclic reactions, transition metal-catalyzed reactions, and cycloadditions. It is ideal for advanced students and researchers working in synthetic organic chemistry in academia and industry.

Contents

1. General Introduction to Comprehensive Aryne Synthetic Chemistry
2. Methods of Generating Arynes
3. Electrophilic Couplings
    3.1 Simple Arylation
    3.2 Insertion into σ-Bonds
    3.3 Multicomponent Reactions
    3.4 Molecular Rearrangements
4 Pericyclic Reactions Including [2+2], [3+2], and [4+2] Cycloadditions
5. Transition Metal-Catalyzed Reactions