Mechanisms of Atmospheric Oxidation of the Oxygenates

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Mechanisms of Atmospheric Oxidation of the Oxygenates

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  • 製本 Hardcover:ハードカバー版/ページ数 1634 p./サイズ 462 illus.
  • 言語 ENG
  • 商品コード 9780199767076
  • DDC分類 551.511

Full Description

Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues.

This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.

Contents

1. The Oxygenates: Their Properties, Sources, and Use as Alternative Fuels ; 2. Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Alcohols ; 3. Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Ethers ; 4. Rate Coefficients and Mechanisms for the Atmospheric Oxidation ; 5. Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Ketonesof the Aldehydes ; 6. Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Organic Acids ; 7. Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Esters ; 8. Rate Coefficients and Mechanisms for Atmospheric Oxidation of N-Atom-Containing Oxygenates ; 9. Mechanisms of Photodissociation of the Sunlight-Absorbing Oxygenates ; 10. The Influence of Oxygenates on the Atmospheric Chemistry of Urban, Rural, and Global Environments ; Appendix. Structures of the Oxygenates Discussed in This Report