Crystalline Molecular Complexes and Compounds : Structures and Principles (International Union of Crystallography Monographs on Crystallography)

Herbstein, Frank H.

Oxford University Press（2005/11発売）

• ページ数 1352 p.
• 言語 ENG
• 商品コード 9780198526605
• DDC分類 548.3

Full Description

This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Perhaps better known as molecular complexes and compounds, these crystals are currently estimated (from molecular recognition studies) to make up one quarter of the world's crystals, providing evidence for some sort of special attraction between the two components. DNA is perhaps the most famous example but others (hydrates, solvates, host-guest inclusion complexes, donor-acceptor compounds) pervade the whole body of solid state chemistry. Although much research has been published, there has never been a comprehensive and unified treatment of the whole field. This book has been designed to fill this gap, comparing and contrasting the various examples and the different types of interaction (hydrogen bonding, inclusion and localized or delocalized charge transfer). More than 600 figures, 200 tables and 3500 references are included in the book. Since most 'parent compounds' form a number of adducts, the fraction of crystalline binary adducts is only going to grow making this account just the 'tip of the iceberg'.

Contents

ONE: SOME PRELIMINARIES ; 1. Structural principles in the classification of binary adducts ; 2. Historical outline ; TWO: MOIETIES WITHIN MOLECULES ; 3. The enclosure molecules - crown ethers, cryptands and related molecules - as hosts ; 4. Cyclodextrins, and some analogues, as hosts ; 5. Crystal chemistry of some DNA oligonucleotides and their complexes ; THREE: HOST-GUEST INCLUSION COMPLEXES ; 6. Channel inclusion complexes formed by hosts of lesser versatility ; 7. Clathrate inclusion complexes formed by hosts of lesser versatility ; 8. Inclusion complexes formed by versatile hosts ; 9. Inter-lamellar complexes ; FOUR: PACKING COMPLEXES ; 10. Packing complexes ; FIVE: MOLECULAR COMPOUNDS WITH LOCALISED INTERACTIONS ; 11. Donor-acceptor molecular compounds (essentially localized interactions) ; 12. Hydrogen-bonded compounds ; SIX: MOLECULAR COMPOUNDS WITH DELOCALISED INTERACTIONS ; 13. General introduction ; 14. Layered molecules with intramolecular donor-acceptor interactions ; 15. Crystal chemistry of mixed stack pi-pi* molecular compounds ; 16. Crystal physics of mixed stack pi-pi* molecular compounds ; 17. Segregated stack pi molecular compounds ; APPENDIX 1. THERMODYNAMIC MEASUREMENTS ON BINARY ADDUCTS.