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Organogermanium Compounds Understand the chemistry of organogermanium compounds with this thorough and cutting-edge reference
Discovered comparatively late in the history of chemistry, germanium has become one of the most technology-critical elements in modern industry. Germanium and its inorganic and organic derivatives found widespread applications in fiber- and infrared-optics, electronics, polymerization catalysis, solar electric technology, nanotechnology, chemotherapy, and more. Organogermanium compounds containing carbon to germanium chemical bonds, have applications in microelectronics, medicinal and health industries, and beyond.
Organogermanium Compounds: Theory, Experiment, and Applications, 2 Volume Set provides a comprehensive review of this class of compounds in two thorough volumes. It covers all modern aspects of these critically important compounds, including theoretical, synthetic, physico-chemical, and applied research. Reflecting the latest breakthroughs in this rapidly growing field, this book promises to serve as the high-level reference for those readers who are interested in organogermanium chemistry.
Organogermanium Compounds readers will also find:
19 chapters produced by leading global experts
Descriptions of pivotal historical achievements in organogermanium research
Coverage of the latest computational, synthetic, and applied breakthroughs
Organogermanium Compounds is a critical reference for researchers and professionals in a wide range of academic and industrial fields working with these fascinating compounds. This will also be helpful for university and college students, at both graduate and undergraduate levels.
Contents
Volume 1
Preface ix
List of Contributors
1 Computational and Theoretical Aspects of Structure and Bonding in Doubly Bonded Organogermanium Compounds 1
Miriam Karni and Yitzhak Apeloig
2 Organogermanium Compounds of the Main Group Elements 103
Kirill V. Zaitsev
3 Transition Metal Complexes of Germanium 195
Kohtaro Osakada
4 Germanium Cages and Clusters 225
Tanja Kunz and Andreas Schnepf
5 Arylgermanium Hydrides, Ar n GeH 4-n (n = 1-3) - Synthesis, Characterization, Reactivity 277
Ana Torvisco and Frank Uhlig
6 Germylium Ions and Germylium Ion-like Species 299
Thomas Müller
7 Germanium-Containing Radicals 339
Alexander Hinz and Frank Breher
8 Germanium-Centered Anions 361
Christoph Marschner
9 Germylenes 387
Norio Nakata xiii
10 Multiple Bonds to Germanium 435
Vladimir Ya. Lee
Volume 2
Preface vii
List of Contributors xi
11 Germaaromatic Compounds 477
Yoshiyuki Mizuhata and Norihiro Tokitoh
12 Germanium-centered Ion Radicals 507
Mikhail P. Egorov, Viatcheslav V. Jouikov, Elena N. Nikolaevskaya, and Mikhail A. Syroeshkin
13 Donor-acceptor Stabilization of Species with Low-coordinate Germanium 561
Sakya S. Sen and Herbert W. Roesky
14 Synthesis of the Penta- and Hexacoordinate Germanium(IV) Complexes 597
Naokazu Kano
15 Dynamic Stereochemistry of Penta- and Hexacoordinate Germanium(IV) Complexes 629
Vadim V. Negrebetsky and Alexander A. Korlyukov
16 X-ray Crystallography of Organogermanium Compounds 667
Catherine Hemmert and Heinz Gornitzka
17 Organogermanium Photochemistry 745
William J. Leigh
18 Oligo- and Polygermanes 787
Charles S. Weinert
19 Bioorganic and Medicinal Organogermanium Chemistry 839
Takashi Nakamura, Yasuhiro Shimada, and Katsuyuki Sato
Index 867
