Description
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Table of Contents
Preface, Contributors, 1. Fundamental Concepts of Coordination Chemistry, 2. Ligands of Modern Coordination Chemistry, 3. Main Methods of the Synthesis of Coordination Compounds, 4. Synthesis of Coordination Compounds with Programmed Properties, 5. Synthesis of Selected Groups of Coordination Compounds, Conclusions, Index
