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基本説明
Describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and more.
Full Description
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Contents
Fundamental concepts of co-ordination chemistry, Alexander D. Garnovskii, Igor S. Vasilchenko, and Dmitry A. Garnovskii; ligands of modern co-ordination chemistry, Alexander D. Garnovskii, Igor S. Vasilchenko, and Dmitry A. Garnovskii; main methods of the synthesis of co-ordination compounds, Alexander D. Garnovskii, Igor S. Vasilchenko, Dmitry A. Garnovskii, and Boris I. Kharisov; synthesis of co-ordination compounds with programmed properties, Alexander D. Garnovskii, Igor S. Vasilchenko, and Dmitry A. Garnovskii; synthesis of selected groups of co-ordination compounds, Boris I. Kharisov, Miguel A. M ndez-Rojas, and Leonor M. Blanco Jerez.